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Energy Change
infoWhy this? Explaining energy transfers in chemical reactions helps us understand heating, cooling, and energy use in everyday, industrial, and biological contexts. Temperature measurements and reaction profiles provide complementary ways to describe exothermic and endothermic changes.
scheduleWhy now? Building on Structure and Bonding, we now examine the energy transfers that accompany chemical change. Reaction profiles and activation energy provide a foundation for explaining the effects of temperature and catalysts in Rates of Reactions.
neurologyYou need to know
- An exothermic reaction transfers energy to the surroundings, so the temperature of the surroundings increases.
- An endothermic reaction takes in energy from the surroundings, so the temperature of the surroundings decreases.
- The surroundings are everything outside the reacting chemicals, such as the solution, beaker, air, or thermometer.
- A reaction is identified as exothermic if the measured temperature of the surroundings rises during the reaction.
- A reaction is identified as endothermic if the measured temperature of the surroundings falls during the reaction.
- In an exothermic reaction, the products have less energy than the reactants.
- In an endothermic reaction, the products have more energy than the reactants.
- The overall energy change is the difference between the energy of the reactants and the energy of the products.
- For an exothermic reaction, the overall energy change is negative because energy is transferred from the chemicals to the surroundings.
- For an endothermic reaction, the overall energy change is positive because energy is transferred from the surroundings to the chemicals.
- Activation energy is the minimum energy needed for particles to react when they collide.
- A reaction profile, or energy level diagram, shows the energy of reactants and products as the reaction progresses.
- In a reaction profile, the activation energy is shown as the energy difference from the reactants to the highest point of the curve.
- In an exothermic reaction profile, the reactants are drawn at a higher energy level than the products.
- In an endothermic reaction profile, the reactants are drawn at a lower energy level than the products.
- Useful applications of exothermic reactions include hand warmers and self-heating cans because they release heat energy.
- Useful applications of endothermic reactions include sports injury cold packs because they take in heat energy from the surroundings.
rocket_launchYou must be able to
- Identify a reaction as exothermic or endothermic from temperature data by deciding whether the temperature of the surroundings increases or decreases.
- Draw an exothermic reaction profile with reactants above products, a curved pathway, labelled activation energy, and a negative overall energy change.
- Draw an endothermic reaction profile with reactants below products, a curved pathway, labelled activation energy, and a positive overall energy change.
- Label the activation energy on a reaction profile as the energy rise from the reactants to the highest point of the curve.
- Label the overall energy change on a reaction profile as the energy difference between the reactants and products.
- Use a reaction profile to classify a reaction as exothermic or endothermic by comparing the relative energies of reactants and products.
- Evaluate an application of an exothermic or endothermic reaction by linking the energy transfer to its usefulness, risks, and practical limitations.